The way I see it.
The only thing I can think of that can turn the refrigerant oil black is heat, excess heat.
If it overheats and breaks down then all lubricating, conditioning.... properties are no longer helping.
It will degrade and degrade taking things down with it.
That's assuming the oil is not the wrong specs which will degrade by being used on the wrong application( severe duty).
The ac compressor as it does, it compresses the refrigerant, this causes it to heat up, this is normal and desirable, but what happens when it gets to high to hot, the refrigerant will degrade little by little. A new design can change that problem. The expansion valve should be replaced for peace of mind.
A friend has a toyota using the same set up. It stopped cooling down so we open it up. The dessicant bag had the 1st inch or so blackened, after replacing the bag and expansion valve the system got set up and filled again with another Oz of oil and It began to cool down again.
I can't say that this will fix the problem but considering that there is fresh oil and a clean bag, I can only hope it extends the life of it for a x time longer.